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971.
972.
Strontium as a tracer of weathering processes in a silicate catchment polluted by acid atmospheric inputs, Strengbach, France 总被引:4,自引:0,他引:4
This paper determines the weathering and atmospheric contributions of Ca in surface water from a small spruce forested silicate catchment (N–E France) receiving acid atmospheric inputs. The bedrock is a granite with K-feldspar and albite as dominant phases. The calcium content in plagioclase is low and the Ca/Na ratio in surface water is high, reflecting other sources of calcium from those expected from the weathering of major mineral phases. The biotite content is low. Only traces of apatite were detected while no calcite was found in spite of a major hydrothermal event having affected the granite. The strontium isotopic ratio 87Sr/86Sr and Sr content was used as a tracer of weathering and was determined in minerals and bulk bedrock, open field precipitation, throughfall, soil solution, spring and stream water. The Sr isotopic ratio of the reacting weathering end-member was predicted by simulating the alteration of the granite minerals by incorporating strontium into the water–rock interaction kinetic code KINDIS. In the early stages of water–rock interaction, K-feldspar and biotite strongly influence the isotopic composition of the weathering solution whereas, the Na-rich plagioclase appears to be the main long-term reactive weathering end-member. Approximately 50% of dissolved Sr in streamwater are atmospherically derived. The 87Sr/86Sr ratios of exchangeable Sr in the fine fraction at 1-m depth from a soil profile indicate that the amount of exchangeable Sr seems essentially controlled by atmospheric inputs. The exception is the deep saprolite where weathering processes could supply the Sr (and Ca). Na-Plagioclase weathering obviously control the chemistry and the isotopic composition of surface waters. The weathering of trace mineral plays a secondary role, the exception is for apatite when plagioclase is absent. Our hydrochemical, mineralogical and isotopic investigations show that a major part of the strong Ca losses detected in catchment hydrochemical budgets that result from the neutralization of acid precipitation has an atmospheric origin. Consequently, in the long term, in such areas, the availability of such an exchangeable base cation might be strongly limited and surface waters consequently acidified. 相似文献
973.
The development of industrial and tourism activities as well as the increase in the urban population in the northwest African region has generally been highly concentrated in the coastal zone. Due to high rates of population growth, urbanisation is likely to increase dramatically in the coming future. This paper presents a physical and socio-economic environmental analysis of the region and highlights the few efforts that have called for the development of co-ordinated strategies in view of integrated coastal zone management. Experience in the implementation of methodologies for adopting integrated coastal zone management strategies in these countries is discussed. 相似文献
974.
Tesfay G. Gebremicael Yasir A. Mohamed Pieter van der Zaag Khalid Hassaballah Eyasu Y. Hagos 《水文研究》2020,34(9):2101-2116
Understanding the natural low flow of a catchment is critical for effective water management policy in semi-arid and arid lands. The Geba catchment in Ethiopia, forming the headwaters of Tekeze-Atbara basin was known for its severe land degradation before the recent large scale Soil and Water conservation (SWC) programs. Such interventions can modify the hydrological processes by changing the partitioning of the incoming rainfall on the land surface. However, the literature lacks studies to quantify the hydrological impacts of these interventions in the semi-arid catchments of the Nile basin. Statistical test and Indicators of Hydrological Alteration (IHA) were used to identify the trends of streamflow in two comparatives adjacent (one treated with intensive SWC intervention and control with fewer interventions) catchments. A distributed hydrological model was developed to understand the differences in hydrological processes of the two catchments. The statistical and IHA tools showed that the low flow in the treated catchment has significantly increased while considerably decreased in the control catchment. Comparative analysis confirmed that the low flow in the catchment with intensive SWC works was greater than that of the control by >30% while the direct runoff was lower by >120%. This implies a large proportion of the rainfall in the treated catchment is infiltrated and recharge aquifers which subsequently contribute to streamflow during the dry season. The proportion of soil storage was more than double compared to the control catchment. Moreover, hydrological response comparison from pre- and post-intervention showed that a drastic reduction in direct runoff (>84%) has improved the low flow by >55%. This strongly suggests that the ongoing intensive SWC works have significantly improved the low flows while it contributed to the reduction of total streamflow in the catchment. 相似文献
975.
976.
Kaolin, cordierite, and calcite are investigated as supports for TiO2. The prepared TiO2/support samples are examined for the removal of organic dyes from wastewater. The samples are preliminarily investigated to identify the optimal loaded system using synthetic wastewater containing methylene blue (MB). Data indicate that the investigated support significantly affects the photocatalytic activity of the supported TiO2. Low photocatalytic activity toward MB degradation is observed upon using TiO2/calcite when compared to the unsupported TiO2. Interaction between calcite and titania species probably occurrs to produce the less photoactive CaTiO3 amorphous species. Anatase TiO2 is obtained upon using kaolin and cordierite as supports. The low photocatalytic performance of the TiO2/kaolin sample is also observed. A high concentration of MB on TiO2/kaolin surfaces blocks the photoactive sites. TiO2/cordierite shows the highest photocatalytic activity compared to the unsupported TiO2 as well as the other TiO2/support samples. Rigid cordierite particles suppress the agglomeration of TiO2 particles during the preparation, leading to a high exposed surface of TiO2 towards light illumination. TiO2/cordierite is investigated for the removal of organic dye from real wastewater collected from a textile dyeing factory. Color removal of up to 46% is achieved upon UV irradiation. 相似文献
977.
An automated cross‐validation method to assess seismic time‐to‐depth conversion accuracy: a case study on the Cooper and Eromanga basins,Australia 下载免费PDF全文
Selecting a seismic time‐to‐depth conversion method can be a subjective choice that is made by geophysicists, and is particularly difficult if the accuracy of these methods is unknown. This study presents an automated statistical approach for assessing seismic time‐to‐depth conversion accuracy by integrating the cross‐validation method with four commonly used seismic time‐to‐depth conversion methods. To showcase this automated approach, we use a regional dataset from the Cooper and Eromanga basins, Australia, consisting of 13 three‐dimensional (3D) seismic surveys, 73 two‐way‐time surface grids and 729 wells. Approximately 10,000 error values (predicted depth vs. measured well depth) and associated variables were calculated. The average velocity method was the most accurate overall (7.6 m mean error); however, the most accurate method and the expected error changed by several metres depending on the combination and value of the most significant variables. Cluster analysis tested the significance of the associated variables to find that the seismic survey location (potentially related to local geology (i.e. sedimentology, structural geology, cementation, pore pressure, etc.), processing workflow, or seismic vintage), formation (potentially associated with reduced signal‐to‐noise with increasing depth or the changes in lithology), distance to the nearest well control, and the spatial location of the predicted well relative to the existing well data envelope had the largest impact on accuracy. Importantly, the effect of these significant variables on accuracy were found to be more important than choosing between the four methods, highlighting the importance of better understanding seismic time‐to‐depth conversions, which can be achieved by applying this automated cross‐validation method. 相似文献
978.
A risk‐based life cycle cost strategy for optimal design and evaluation of control methods for nonlinear structures 下载免费PDF全文
The lack of direct correspondence between control objectives and hazard risks over the lifetime of systems is a key shortcoming of current control techniques. This along with the inability to objectively analyze the benefits and costs of control solutions compared with conventional methods has hindered widespread application of control systems in seismic regions. To address these gaps, this paper offers 2 new contributions. First, it introduces risk‐based life cycle–cost (LCC) optimal control algorithms, where LCC is incorporated as the performance objective in the control design. Two strategies called risk‐based linear quadratic regulator and unconstrained risk‐based regulator are subsequently proposed. The considered costs include the initial cost of the structure and control system, LCC of maintenance, and probabilistically derived estimates of seismic‐induced repair costs and losses associated with downtime, injuries, and casualties throughout the life of the structure. This risk‐based framework accounts for uncertainties in both system properties and hazard excitations and uses outcrossing rate theory to estimate fragilities for various damage states. The second contribution of this work is a risk‐based probabilistic framework for LCC analysis of existing and proposed control strategies. The proposed control designs are applied to the nonlinear model of a 4‐story building subjected to seismic excitations. Results show that these control methods reduce the LCC of the structure significantly compared with the status quo option (benefits of up to $1 351 000). The advancements offered in this paper enhance the cost‐effectiveness of control systems and objectively showcase their benefits for risk‐informed decision making. 相似文献
979.
The seismic response of rocking frames that consist of a rigid beam freely supported on rigid freestanding rectangular piers has received recent attention in the literature. Past studies have investigated the special case where, upon planar rocking motion, the beam maintains contact with the piers at their extreme edges. However, in many real scenarios, the beam‐to‐pier contact lies closer to the center of the pier, affecting the overall stability of the system. This paper investigates the seismic response of rocking frames under the more general case which allows the contact edge to reside anywhere in‐between the center of the pier and its extreme edge. The study introduces a rocking block model that is dynamically equivalent to a rocking frame with vertically symmetric piers of any geometry. The impact of top eccentricity (ie, the distance of the contact edge from the pier's vertical axis of symmetry) on the seismic response of rocking frames is investigated under pulse excitations and earthquake records. It is concluded that the stability of a top‐heavy rocking frame is highly influenced by the top eccentricity. For instance, a rocking frame with contacts at the extreme edges of the piers can be more seismically stable than a solitary block that is identical to one of the frame's piers, while a rocking frame with contacts closer to the centers of the piers can be less stable. The concept of critical eccentricity is introduced, beyond which the coefficient of restitution contributes to a greater reduction in the response of a frame than of a solitary pier. 相似文献
980.
Mapping groundwater recharge potential zones in arid region using GIS and Landsat approaches,southeast Tunisia 总被引:1,自引:0,他引:1
Dhekra Souissi Mohamed Haythem Msaddek Lahcen Zouhri Ismail Chenini Moufida El May Mahmoud Dlala 《水文科学杂志》2018,63(2):251-268
The rapid growth of population and agricultural and industrial activities has caused an increase in demand on the Jeffara aquifers of Gabes (southeast Tunisia). In fact, the over-pumping of this aquifer system has resulted in water-level declines ranging from 0.25 to 1 m/year during the past three decades. The aim of this study is to identify favourable artificial recharge sites of this aquifer system based on the combined use of remotely sensed data, a geographic information system (GIS), the Shuttle Radar Topography Mission (SRTM) product and a multiple criteria decision making (MCDM) technique. The delineation of artificial recharge zones shows high to moderate potential for groundwater recharge (40%) in the Gabes region, with high precision of good potential proposed sites. Recharge processes need to account for natural conditions and ecosystems. 相似文献